Valid 08/2001 - 10/2001
Aldrich Chemical Co., Inc.
1001 West St. Paul
Milwaukee, WI 53233 USA
Tel: 414-273-3850
M A T E R I A L S A F E T Y D A T A S H E E T
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: N29406
NAME: NONANE, 99%
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 111-84-2
MF: C9H20
EC NO: 203-913-4
SYNONYMS
N-NONANE * NONANE (ACGIH) * SHELLSOL 140 *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
FLAMMABLE
HARMFUL
HARMFUL BY INHALATION.
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
VAPORS MAY CAUSE DROWSINESS AND DIZZINESS.
TARGET ORGAN(S):
CENTRAL NERVOUS SYSTEM
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
DO NOT BREATHE VAPOR.
WEAR SUITABLE GLOVES.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN IMMEDIATELY.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IN CASE OF SKIN CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND
SHOES. CALL A PHYSICIAN.
IN CASE OF CONTACT WITH EYES, FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING
THE EYELIDS WITH FINGERS. CALL A PHYSICIAN.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHMENT.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND
FLASH BACK.
CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
COVER WITH DRY-LIME, SAND, OR SODA ASH. PLACE IN COVERED CONTAINERS
USING NON-SPARKING TOOLS AND TRANSPORT OUTDOORS.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
EVACUATE AREA.
SHUT OFF ALL SOURCES OF IGNITION.
USE NONSPARKING TOOLS.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
SAFETY SHOWER AND EYE BATH.
USE NONSPARKING TOOLS.
MECHANICAL EXHAUST REQUIRED.
WASH THOROUGHLY AFTER HANDLING.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
DO NOT BREATHE VAPOR.
AVOID PROLONGED OR REPEATED EXPOSURE.
NIOSH/MSHA-APPROVED RESPIRATOR.
COMPATIBLE CHEMICAL-RESISTANT GLOVES.
CHEMICAL SAFETY GOGGLES.
KEEP CONTAINER CLOSED.
KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
PHYSICAL PROPERTIES
BOILING POINT: 150 - 151 C
MELTING POINT: -53 C
FLASHPOINT 87.80F
31C
EXPLOSION LIMITS IN AIR:
UPPER 2.9 %
LOWER 0.87 %
VAPOR PRESSURE: 9.306 MMHG
SOLUBILITY:
WATER -Z1077
SPECIFIC GRAVITY: 0.718
VAPOR DENSITY: 4.41 G/L
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
STABILITY
STABLE.
INCOMPATIBILITIES
SENSITIVE TO MOISTURE
STRONG OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
CARBON MONOXIDE, CARBON DIOXIDE
HAZARDOUS POLYMERIZATION
WILL NOT OCCUR.
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
CAUSES SKIN IRRITATION.
MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
CAUSES EYE IRRITATION.
HARMFUL IF INHALED.
VAPOR OR MIST IS IRRITATING TO THE MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
MAY BE HARMFUL IF SWALLOWED.
CHRONIC EFFECTS
TARGET ORGAN(S):
CENTRAL NERVOUS SYSTEM
RTECS #: RA6115000
NONANE
TOXICITY DATA
IHL-RAT LC50:3200 PPM/4H TXAPA9 44,53,1978
IVN-MUS LD50:218 MG/KG JPMSAE 67,566,1978
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF
THIS MATERIAL.
BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND
SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY
FLAMMABLE.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
FLAMMABLE
HARMFUL
R 10
FLAMMABLE.
R 20
HARMFUL BY INHALATION.
R 66
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
R 67
VAPORS MAY CAUSE DROWSINESS AND DIZZINESS.
S 16
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
S 23
DO NOT BREATHE VAPOR.
S 37
WEAR SUITABLE GLOVES.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
ACGIH TLV-TWA 200 PPM DTLVS* TLV/BEI,1999
OEL-DENMARK: TWA 200 PPM (1050 MG/M3), JAN1999
OEL-FINLAND: TWA 200 PPM (1050 MG/M3), STEL 250 PPM (1315 MG/M3),
JAN1999
OEL-FRANCE: VME 200 PPM (1050 MG/M3), JAN1999
OEL-JAPAN: OEL 200 PPM (1050 MG/M3), JAN1999
OEL-THE NETHERLANDS: MAC-TGG 0.05 PPM (0.5 MG/M3), SKIN, JAN1999
OEL-NORWAY: TWA 100 PPM (525 MG/M3), JAN1999
OEL-SWEDEN: NGV 150 PPM (800 MG/M3), KTV 200 PPM (1100 MG/M3), JAN1999
OEL-SWITZERLAND: MAK-W 200 PPM (1050 MG/M3), JAN1999
OEL-UNITED KINGDOM: TWA 0.1 MG(SN)/M3, STEL 0.2 MG(SN)/M3, SKIN,
SEP2000
OEL IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV;
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV
NIOSH REL TO NONANE-AIR:10H TWA 200 PPM
NIOSH* DHHS #92-100,1992
NOHS 1974: HZD M4718; NIS 2; TNF 57; NOS 2; TNE 1231
NOES 1983: HZD M4718; NIS 14; TNF 738; NOS 16; TNE 7277; TFE 717
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JANUARY 2001
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 2001 SIGMA-ALDRICH CO.
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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