PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 133K Anti-seize Lubricant 80078 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: 133K Anti-seize Lubricant Item No.: 80078 Part No.: 133K Product Type: Lubricant 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Mineral oil 64742-52-5 40-50 COPPER* 7440-50-8 10-15 GAS OIL 64741-44-2 10-15 ALUMINUM 7429-90-5 5-10 Mineral oil, petroleum distillates 64742-53-6 0-10 Graphite 7782-42-5 1-3 Lithium soap 7620-77-1 1-3 SILICA, AMORPHOUS, precipitated 112926-00-8 1-3 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Mineral oil 5 mg/m3 mist 5 mg/m3 mist 5 mg/m3 mist COPPER 1 mg/m3 dust 1 mg/m3 dust None GAS OIL 5mg/m3 TWA mist 5mg/m3 TWA mist None ALUMINUM 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir. Mineral oil, petroleum distillates 5 mg/m3 mist 5 mg/m3 mist None Graphite 2.5 mg/m3 dust, 2.5 mg/m3 dust, None respirable respirable SILICA, AMORPHOUS, precipitated 10 mg/m3 TWA 6 mg/m3 TWA None Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) Mineral oil 10 mg/m3 mist None GAS OIL 10 mg/m3 mist None Mineral oil, petroleum distillates 10 mg/m3 mist None PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: 133K Anti-seize Lubricant Item No.: 80078 3. HAZARDS IDENTIFICATION Toxicity: May irritate eyes or skin. Vapors or direct contact may irriate or burn nose and throat. Swallowing may irritate digestive tract and cause nervous system depression. Prolonged skin contact with copper may cause sensitization dermatitis. Copper dusts and mists are eye and mucous membrane irritants and skin sensitizers. Swallowing copper compounds may cause vomiting and collapse. Target organs include respiratory system, nasal septum, skin, eyes, gastrointestinal system, kidneys, liver, and cardiovascular system. Primary Routes of Entry: Ingestion, inhalation, skin and eye contact. Signs and symptoms of Exposure: May cause skin or eye irritation with prolonged or repeated contact. Metal-fume fever, metallic taste, discoloration of skin or hair may indicate exposure to copper. Hemolysis, jaundice, anuria, hypotension, and convulsions may indicate acute copper poisoning. Existing Conditions Aggravated by Exposure: Graphite powder: emphysema, asthma, and other respiratory problems. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Mineral oil IRR NO NO NO COPPER BLO CNS GAS IMM IRR KID LIV MUT NO NO NO SEN SKI GAS OIL No Data NO NO NO ALUMINUM IRR LUN NO NO NO Mineral oil, petroleum distillates IRR NO NO NO Graphite LUN NO NO NO Lithium soap No Data NO NO NO SILICA, AMORPHOUS, precipitated NUI NO NO NO ------------------------------------------------------------------------------- Abbreviations BLO Blood CNS Central nervous system GAS Gastrointestinal IMM Immune system IRR Irritant KID Kidney LIV Liver LUN Lung MUT Mutagen NUI Nuisance dust SEN Sensory SKI Skin PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: 133K Anti-seize Lubricant Item No.: 80078 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Oil mist: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Flush with water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: None Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Metal vapors, oxides of carbon, nitrogen, barium, zinc, sulfur; hydrogen sulfide. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower 30% Aluminum metal 1% Gas oil (% by volume in air)Upper Unknown Aluminum metal 7% Gas oil 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Remove sources of ignition. Take up with an inert absorbent. Store in a closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Keep away from sources of ignition and hot surfaces. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Keep away from eyes. Avoid prolonged skin contact. Avoid prolonged breathing of vapors. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Neoprene or oil resistant plastic gloves. Ventilation: Provide adequate local ventilation to maintain vapor concentration below TLV if misting of oil occurs or compound becomes dry. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: 133K Anti-seize Lubricant Item No.: 80078 8. EXPOSURE CONTROLS, PERSONAL PROTECTION (continued) See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Grey grease Odor: Petroleum Boiling Point: More than 500°F pH: Does not apply Solubility in Water: Nil Specific Gravity 1.1242 Volatile Organic Compound (EPA Method 24) 10.66%; 122 grams per liter Vapor Pressure: Less than 5mm at 80°F Vapor Density: Approximately 2.9 Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers, alkalies, mineral acids, selected amines. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): Noxious carbon compounds, hydrogen. 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. Do not incinerate pressurized cans. EPA Hazardous Waste Number NH - Not a RCRA Hazardous waste material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: 133K Anti-seize Lubricant Item No.: 80078 14. TRANSPORTATION INFORMATION (continued) Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: No Prop65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 22, 1996 Revision: 0032