LOCTITE CORPORATION 05/06/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Loctite(R) Industrial Fast Orange(R) Pumice 35013 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Loctite(R) Industrial Fast Orange(R) Pumice Cream Hand Cleaner Item No.: 35013 Part No.: 35-013 Product Type: Industrial Waterless Handcleaner 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Water 7732-18-5 65-75 Pumice 1332-09-8 5-10 Terpenes and terpenoids, sweet orange-oil 68647-72-3 5-10 d-Limonene 5989-27-5 *** Poly(oxy-1,2-ethanediyl), a-un decyl-w-hydroxy, 127036-24-2 1-5 Propylene glycol 57-55-6 1-5 Vegetable oil Proprietary 1-5 Acrylic acid polymer 9003-01-4 0.1-1 SILICA, QUARTZ 014808-60-7 0.1-1 Triethanolamine Proprietary 0.1-1 ***d-Limonene is a major fraction of the sweet orange oil terpenes/terpenoids. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Pumice 10 mg/m3(Ihnal) 15 mg/m3(Total) None 3 mg/m3 (Resp) 5 mg/m3 (Resp) d-Limonene None None 30 ppm SILICA, QUARTZ 0.1 mg/m3 TWA 0.1 mg/m3 TWA None respirable dust respirable dust Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) LOCTITE CORPORATION 05/06/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Loctite(R) Industrial Fast Orange(R) Pumice Cream Hand Cleaner Item No.: 35013 3. HAZARDS IDENTIFICATION Toxicity: Estimated oral LD50 more than 5000 mg/kg Primary irritation tests show that this product is not a primary irritant. Primary Routes of Entry: Skin contact, ingestion, and inhalation. Signs and Symptoms of Exposure: None under normal conditions of use. Existing Conditions Aggravated by Exposure: None known Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Water NTO NO NO NO Pumice NTO NO NO NO Terpenes and terpenoids, sweet orange-oil No Data NO NO NO d-Limonene IRR NO N/A NO Poly(oxy-1,2-ethanediyl), a-un decyl-w-hydroxy, No Data NO NO NO Propylene glycol IRR NO NO NO Vegetable oil IRR NO NO NO Acrylic acid polymer NTO NO N/A NO SILICA, QUARTZ LUN SOM YES 2A NO Triethanolamine No Data NO NO NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2A Probably carcinogenic to humans IRR Irritant LUN Lung NTO No Target Organs SOM Evidence of some carcinogenicity 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Call physician immediately Inhalation: Remove to fresh air.If symptoms persist, obtain medical attention. Skin Contact: Flush with water. Eye Contact: Flush at least 15 minutes with water. Call physician immediately. LOCTITE CORPORATION 05/06/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Loctite(R) Industrial Fast Orange(R) Pumice Cream Hand Cleaner Item No.: 35013 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Recommended Extinguishing Agents: Carbon dioxide, chemical powder Special Firefighting Procedures: Not available Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Rinse away with water or wipe up with a towel. 7. HANDLING AND STORAGE Safe Storage: Hand cleaner should be stored between 40°F and 100°F (Contact Loctite Customer Service 1-800-243-4874 for shelf life information) Handling: Follow all general safety precautions. Keep away from children. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Not normally needed, but safety glasses offer increased protection. Skin: None normally needed. Ventilation: Some local ventilation may be desired for prolonged exposure in a confined area. Respiratory Not available See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White cream with Pumice Odor: Orange Boiling Point: Not Available pH: 7.0 Solubility in Water: Soluble Specific Gravity 1.01 LOCTITE CORPORATION 05/06/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Loctite(R) Industrial Fast Orange(R) Pumice Cream Hand Cleaner Item No.: 35013 9. PHYSICAL AND CHEMICAL PROPERTIES (continued) Volatile Organic Compound (EPA Method 24) 11.2%; 113 grams per liter of material Vapor Pressure: Not available Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Dispose of uncontaminated material through sewage system with permission of the authority responsible for that system. Follow EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None LOCTITE CORPORATION 05/06/01 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Loctite(R) Industrial Fast Orange(R) Pumice Cream Hand Cleaner Item No.: 35013 15. REGULATORY INFORMATION CA Proposition 65: No California Proposition 65 chemicals are known to be present at or above the No Signifificant Risk level. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1 Flammability Hazard: 1 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: C. J. Michaels. Title: Health and Safety Dept. Company: Loctite Corp., 1001 Trout Brook Crossing, Rocky Hill, CT 06067. (24hr.) Phone: (860) 571-5100 Revision Date: November 16, 2000 Revision: 0002