AMERADA HESS -- #6 RESIDUAL FUEL OIL (ALL SULFUR GRADES) - FUEL OIL,BURNER MATERIAL SAFETY DATA SHEET NSN: 9140002474354 Manufacturer's CAGE: 4N716 Part No. Indicator: C Part Number/Trade Name: #6 RESIDUAL FUEL OIL (ALL SULFUR GRADES) =========================================================================== General Information =========================================================================== Item Name: FUEL OIL,BURNER Company's Name: AMERADA HESS CORP Company's Street: 1 HESS PLAZA Company's City: WOODBRIDGE Company's State: NJ Company's Country: US Company's Zip Code: 07095 Company's Emerg Ph #: 800-424-9300(CHEMTREC) Company's Info Ph #: 908-750-6000 Distributor/Vendor # 1: AMERADA HESS CORP (908-750-6000) Distributor/Vendor # 1 Cage: 4N717 Record No. For Safety Entry: 010 Tot Safety Entries This Stk#: 016 Status: FE Date MSDS Prepared: 18JAN94 Safety Data Review Date: 08SEP94 Supply Item Manager: KY MSDS Serial Number: BTWPP Specification Number: ASTM-D-396 Spec Type, Grade, Class: GR 6 Hazard Characteristic Code: F8 Unit Of Issue: GL Unit Of Issue Container Qty: BULK Type Of Container: BULK Net Unit Weight: BULK =========================================================================== Ingredients/Identity Information =========================================================================== Proprietary: NO Ingredient: FUEL OIL #6 RESIDUAL Ingredient Sequence Number: 01 Percent: 100 NIOSH (RTECS) Number: LS8960000 CAS Number: 68476-33-5 OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED Other Recommended Limit: NONE RECOMMENDED ------------------------------------- Proprietary: NO Ingredient: HYDROGEN SULFIDE (SARA III) Ingredient Sequence Number: 02 Percent: N/GIVEN NIOSH (RTECS) Number: MX1225000 CAS Number: 7783-06-4 OSHA PEL: C 20 PPM; Z-2 ACGIH TLV: 10 PPM/15 STEL; 9394 Other Recommended Limit: NONE RECOMMENDED ------------------------------------- Proprietary: NO Ingredient: H2S MAY BE PRESENT IN TRACE AMTS & HIGHLY VARIABLE & UNPREDICTABLE.DOESN'T CORRELATE W/SULFUR CONTENT. Ingredient Sequence Number: 03 Percent: N/A NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED Other Recommended Limit: NONE RECOMMENDED =========================================================================== Physical/Chemical Characteristics =========================================================================== Appearance And Odor: VERY VISCOUS,BLACK LIQ,MAYBE SOLID @ RT,CHARACTER HEAVY PETROLEUM/ASPHALT ODOR. Boiling Point: >500F,>260C Vapor Pressure (MM Hg/70 F): <0.0001 Vapor Density (Air=1): 1.0 Specific Gravity: 0.97 (VARIES) Evaporation Rate And Ref: NEGLIGIBLE. Solubility In Water: NEGLIGIBLE. Percent Volatiles By Volume: NEGLI. Autoignition Temperature: 765F =========================================================================== Fire and Explosion Hazard Data =========================================================================== Flash Point: 150F,66C (MIN) Flash Point Method: PMCC Extinguishing Media: OSHA/NFPA CLASS II COMBUST LIQ.SM:DRY CHEM,CARBON DIOXIDE,WATER SPRAY,FIREFIGHTING FOAM,HALON.LG:WATER SPRAY,FOG,FOAM. Special Fire Fighting Proc: WEAR SCBA W/FULL FACEPIECE/CLOTH WHEN FIRE RESULTS IN HIGH HEAT/SMOKE/TOXIC COMBUST PRODUCTS.FLUSH AWAY SPILLS FROM FIRE & COOL CNTNRS W/WATER.USE TRAIN PERSONS Unusual Fire And Expl Hazrds: HEATED TO FP & MIXED W/AIR & EXPOSED TO IGN SOURCES FLAMM VAP BURN/EXPLODE IN CONFINED AREA.VAP TRAVEL DISTANCES & CAN FLASHBACK.RUNOFF TO SEWER FIRE/EXP HAZ. =========================================================================== Reactivity Data =========================================================================== Stability: YES Cond To Avoid (Stability): MATL STABLE UNDER NORMAL CONDITIONS.AVOID HIGH TEMPS,OPEN FLAMES,WELDING,SMOKING,SPARKS, & IGNITION SOURCES. Materials To Avoid: KEEP AWAY FROM STRONG OXIDIZERS, IGNITIONS SOURCES & HEAT. Hazardous Decomp Products: CARBON MONOXIDE AND CARBON DIOXIDE, SULFUR DIOXIDE AND ACRID SMOKE. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT APPLICABLE. =========================================================================== Health Hazard Data =========================================================================== LD50-LC50 Mixture: LD50 (ORAL, RAT)>5G/KG ESTIMATED. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: NO Health Haz Acute And Chronic: SLIGHT EYE IRRIT;SERIOUS BURNS & BLINDNESS FROM HOT OIL.SLIGHT-MOD SKIN IRRIT,DEFAT LEADING TO 2ND INFECTION FROM PROL/REP CONTACT;SWOLLEN TISSUE,PERM DAMAGE,DEATH FROM HI PRESS SKIN INJECT W/O TREATMENT;1ST,2ND,3RD BURNS.INGEST LG AMTS:GI DISTURBANCES,ASPIRATION INTO LUNGS.INHAL:RESP & CNS IRRIT.LIV/KID/BONEMARR CHANG Carcinogenicity - NTP: NO Carcinogenicity - IARC: YES Carcinogenicity - OSHA: NO Explanation Carcinogenicity: PER MSDS:IARC DETERMINED SUFFICINET EVIDENCE OF CARCI IN EXPERIMENTAL ANIMALS BUT INADEQUATE EVIDENCE IN HUMANS. Signs/Symptoms Of Overexp: EYE:REDNESS,TEARING,BLURRED VISION(FROM ABRASION/RUBBING).SKIN:REDNESS,ITCHING,INFLAMM,CRACKING,DERM(RASH),2ND IRRIT,NAU,VOMIT,DIARR.INHAL:EXCITATION,EUPHORIA,DIZZ,DROWSINESS,HEAD, BLURRED VISION,FATIGUE,TREMORS,CONVULS,COMA,RESP ARREST, Med Cond Aggravated By Exp: IRRITATION FROM SKIN EXPOSURE MAY AGGRAVATE EXISTING DERMATITIS (RASH) CONDITIONS. Emergency/First Aid Proc: EYE:IMMED FLUSH W/CLEAN LOWPRESS WATER FOR @ LEAST 15MINS OPENING EYELIDS.SKIN:REMOVE CONTAMIN CLOTH.IMMED SEE DR FOR HI PRESS INJECT & THERM BURNS.INGEST:DO NOT INDUCE VOMIT.RINSE MOUTH W/WATER. GIVE 1-2 GLASSES OF WATER OR MILK.IF VOMIT LEAN VICTIM FORWARD.INHAL:REMOVE TO FRESH AIR.NOT BREATH GIVE CPR.PROVIDE AIR/OXY ONCE BREATH RESTORED IF TRAINED TO DO SO.IN ALL CASES GET MED ATTN. =========================================================================== Precautions for Safe Handling and Use =========================================================================== Steps If Matl Released/Spill: ACTIVATE SPILL CONTINGENCY PLAN.SECURE IGN SOURCES.H2S SHOULD PRESENT PROBLEM IN CONFINED AREA NOT OPEN AREA.STAY UPWIND.DIKE TO PREVENT SPILL INTO SEWER/WATERWAYS.TAKEUP W/SAND/OTHER OIL ABSORBING MATL.HOT LIQ HAZ.USE PROPER PROTECTIVE EQMPT. Neutralizing Agent: NONE SPECIFIED BY MFG. Waste Disposal Method: MAX PRODUCT RECOVERY FOR REUSE/RECYCLE.PRODUCT NOT LISTED/CHARACTERISTIC HAZ WASTE UNDER FED REGS.CONSULT STATE & LOCAL REGS. COMBUSTION PRODUCTS(ASH)MAYBE CHARACTERISTIC HAZ WASTE.KEEP OUT OF SEWAGE/ DRAINAGE/WATERWAYS.REPORT SPILL/RELEASE PER ALL REG Precautions-Handling/Storing: TRANSP/STORED HOT.HANDLE AS COMBUST LIQ.KEEP CNTNRS CLSD & CLEARLY LABELED.GROUND DRUMS/TRANSFER VESSELS WHEN HANDLING. AVOID BREAHTING VAPORS. Other Precautions: USE APPROVED VENTED CNTNRS.EMPTY CNTNRS/VESS MAY CONTAIN EXPLOSIVE VAP.USE ONLY W/ADEQUATE VENTI.STORE IN WELL-VENTIL AREA & IAW NFPA 30.H2S ACCUM IN TANKS/BULK COMPARTMENTS-CONSIDER RESP PROTECTION. FOLLOW SLOW LOAD STEPS FOR SWITCH LOADING =========================================================================== Control Measures =========================================================================== Respiratory Protection: REFER TO OSHA 29CFR1910.134, ANSI Z88.2-1992, & NIOSH RESP DECISION LOGIC.NIOSH/MSHA APPROVED AIR PURIFYING RESP W/ORG VAP CARTRIDGES/CANISTER,+ PRESS AIR SUPPLIED RESP,SCBA OR TYC SUPPLIED AIR RESP W/ESCAPE BTL:CONSIDER OCCUP EXPO LIMITS. Ventilation: USE ADEQUATE VENT FOR VAP/MIST CONCEN BELOW TLV.CONFINED AREAS:LOC & GEN VENTIL.USE EXPLO-PROOF GEN VENT & LIGHTING. Protective Gloves: NEOPRENE, NITRILE GLOVES. Eye Protection: SAFETY GLASS, GOGGLES. Other Protective Equipment: CHEM PROTECTIVE CLOTHING (POLYCOATED TYVEK QC, SARANEX,EQUIVALENT).PROTECT AGAINST HOT LIQ.EYEWASH,WATERLESS HAND CLEANER Work Hygienic Practices: USE GOOD PERSONAL HYGIENE PRACTICES.WASH CONTAMIN CLOTH PRIOR TO REUSE.CONSIDER DISCARDING CONTAMIN LEATHER SHOE/GLOVES. Suppl. Safety & Health Data: GENERALLY TRANSPORTED HOT. VAP CAN BUIDUP IN HEADSPACE OF TANKS PRESENTING FLAMM/EXPLOSION HAZ. SEE API PUBLICATION 2003,API RECOMMENDED PRACTICE (RP) 2013 & 2015 FOR SAFETY ON IGNITION FROM STATIC & PRACTICE IN CLEANING TANKS. FROM STUDIES 1PPM H2S IN LIQ MAY PRODUCE 100PPM OR MORE H2S IN VAP HEADSPACE OF STORAGE TANK =========================================================================== Transportation Data =========================================================================== Trans Data Review Date: 94251 DOT PSN Code: GOD DOT Symbol: D DOT Proper Shipping Name: FUEL OIL DOT Class: 3 DOT ID Number: NA1993 DOT Pack Group: III DOT Label: FLAMMABLE LIQUID IMO PSN Code: HIA IMO Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. o IMO Regulations Page Number: 3345 IMO UN Number: 1993 IMO UN Class: 3.3 IMO Subsidiary Risk Label: - IATA PSN Code: MCA IATA UN ID Number: 1993 IATA Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. * IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID AFI PSN Code: MMK AFI Symbols: D AFI Prop. Shipping Name: FUEL OIL (NO. 1, 2, 4, 5, OR 6); AFI Class: 3 AFI ID Number: NA1993 AFI Pack Group: III AFI Basic Pac Ref: 7-7 Additional Trans Data: PER MSDS:PROPER SHIPPING NAME FUEL OIL NO.6, HAZ CLASS 3, NA1993, COMBUST LIQ. NO IMO/IATA CODES FOR THIS SO USED FLAMM LIQ NOS PG III. =========================================================================== Disposal Data =========================================================================== =========================================================================== Label Data =========================================================================== Label Required: YES Technical Review Date: 08SEP94 Label Status: F Common Name: #6 RESIDUAL FUEL OIL (ALL SULFUR GRADES) Signal Word: WARNING! Acute Health Hazard-Moderate: X Contact Hazard-Moderate: X Fire Hazard-Moderate: X Reactivity Hazard-None: X Special Hazard Precautions: EYE/SKIN IRRIT;SERIOUS BURNS,BLINDNESS FROM HOT OIL.DEFAT OF SKIN LEADING TO 2ND INFECTION FROM PROL/REP CONTACT; SWOLLEN TISSUE,PERM DAMAGE,DEATH FROM HI PRESS SKIN INJECT W/O MED ATTN; 1ST-3RD BURNS.INGEST LG AMTS:GI IRRIT,ASPIRATION INTO LUNGS.INHAL:RESP/CNS IRRIT.LIV/KID/BONEMARR CHANGE.1STAID:EYE:IMMED FLUSH W/WATER FOR @ LEAST 15MINS OPENING EYELIDS.SKIN:REMOVE CONTAMIN CLOTH.IMMED SEE DR FOR HI PRESS INJECT & THERM BURNS.INGEST:DO NOT INDUCE VOMIT.RINSE MOUTH W/WATER.GIVE 1- 2 GLASSES OF WATER OR MILK.IF VOMIT LEAN VICTIM FORWARD.INHAL:REMOVE TO FRESH AIR.NOT BREATH GIVE CPR.PROVIDE AIR/OXY ONCE BREATH RESTORED.IN ALL CASES GET MED ATTN. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: AMERADA HESS CORP Label Street: 1 HESS PLAZA Label City: WOODBRIDGE Label State: NJ Label Zip Code: 07095 Label Country: US Label Emergency Number: 800-424-9300(CHEMTREC) Year Procured: 1994